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One popular use of the Mail Merge feature is to create envelopes. Mail Merge allows you to set up one mailing envelope, which is used as the starting document for the merge. Using data from a table or external database, you can print that one envelope with different information for each record in the database or table.
These instructions assume that you have an understanding of the Word Mail Merge process. If you would like more information, refer to Mail Merge: An Overview.
The process of creating mail merge envelopes is begun by setting up your starting document. When creating envelopes, you have many options. You can choose the envelope size, text font, positioning of the address, and much more to suit the needs of your particular project.
From the Mailings tab, in the Start Mail Merge group, click START MAIL MERGE
The Start Mail Merge sub-menu appears.
Select Envelopes...

The Envelope Options dialog box appears.
Select the Envelope Options tab
From the Envelope size pull-down list, select your envelope size
Click OK
Click OK
Click OK
Your document is formatted to the proper specifications.
In the Start Mail Merge group, click SELECT RECIPIENTS » select Use Existing List...

The Select Data Source dialog box appears.
From the Look in pull-down list, locate and select the file you will use for your list
Click OPEN
Click OK
NOTE: To edit the recipient information, refer to Working with the Recipients List.
In the Write & Insert Fields group, click INSERT MERGE FIELD » select the desired field

When finished, click PREVIEW RESULTS
A preview of your first recipient's envelope appears.
NOTE: For more information on editing the recipient information, refer to Working with the Recipients List.
OPTIONAL: To preview your document with other recipients' information, in the Preview Results section, click the arrows